Uranium Adsorption on Three Nanohydroxyapatites Under Various Biogeochemical Conditions
Water, Air, and Soil Pollution, cilt.232, sa.9, 2021 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 232 Sayı: 9
- Basım Tarihi: 2021
- Doi Numarası: 10.1007/s11270-021-05298-7
- Dergi Adı: Water, Air, and Soil Pollution
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, ABI/INFORM, Agricultural & Environmental Science Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Compendex, EMBASE, Environment Index, Geobase, Greenfile, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
- Anahtar Kelimeler: Adsorption, Carbonate, Hydroxyapatite, pH effect, Uranium
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Ankara Yıldırım Beyazıt Üniversitesi Adresli: Hayır
Özet
Uranium is a naturally occurring trace element and radionuclide. Uranium is introduced in the environment during industrial activities and nuclear energy accidents involving nuclear power plants, nuclear weapons tests, ore mining, and manufacturing, which may lead to the contamination of groundwater and soil. Hydroxyapatite (HAP) is a natural mineral with a high affinity for uranium in water. Groundwater often contains high carbonate concentrations that may affect uranium removal due to the formation of uranyl carbonate complexes. In order to understand the process of uranium removal, uranium adsorptions on three nano-HAPs were conducted under various biogeochemical conditions. Results showed that the fastest U adsorption occurred onto nano-HAP and U adsorption was strongly affected by biogeochemical conditions such as pH and the presence of carbonates, but less affected by temperature. The current study indicates that the presence of carbonates at pH’s above the neutral range in groundwater may inhibit U removal with nanohydroxyapatites.