Fabrication of La2Zr2O7 buffer layers on Ni tapes by reel-to-reel sol-gel technique
Materials Science and Engineering B: Solid-State Materials for Advanced Technology, vol.106, no.2, pp.182-190, 2004 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 106 Issue: 2
- Publication Date: 2004
- Doi Number: 10.1016/j.mseb.2003.09.019
- Journal Name: Materials Science and Engineering B: Solid-State Materials for Advanced Technology
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.182-190
- Keywords: Alkoxides, Annealing, Buffer layers, HTS, LZO, Ni tape, Sol-gel, TEA, Texture, YBCO
- Ankara Yıldırım Beyazıt University Affiliated: No
Abstract
In order to investigate the optimal conditions for highly orientated and epitaxial buffer layers on textured Ni tapes, we have deposited perovskite textured La2Zr2O7 (LZO) films on Ni tapes using a reel-to-reel sol-gel process for fabrication of second generation high-Tc superconductors. Of these usual parameters, precursor types, solvents, chelating agents, and annealing conditions were chosen to prepare LZO solutions. This effect on epitaxial growth of LZO of these processing and texturing parameters was evaluated using X-ray diffraction (XRD), environment scanning electron microscopy (ESEM), energy dispersive spectrometry (EDS) and orientation imaging microscope (OIM), atomic force microscope (AFM) and X-ray pole figure analysis. Based on the following results, we have found textured, homogenous, dense, crack free and pinhole free, LZO films with a strong c-axis orientation on textured Ni tapes by post-annealing at 1150°C for 10min under 4% H2-Ar gas flow. © 2003 Elsevier B.V. All rights reserved.